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Such limitations on space to get anywhere near 0.18 look to be in the land of aerogels/VIPs. I'd suggest speaking to your/an architect to spec
Hi I tried to edit my last reply - but the changes didn't come through.
You have not mentioned any insulation below the rafters. This is where the gains are made if you must use PIR/PUR, etc. You'd be looking at >100mm below the rafters. There are a host of u value calculators on line to help you. As Robert says, you could also speak to your insulation manufacturer. Make sure you have any cold bridges sorted.
If you are restricted to 50mm, then as I say you should look at super-performance materials such as aerogels or VIPS to give you any chance of meeting 0.18.
I would recommend you give a specialist like Kingspan a call and ask to speak to someone in their technical department. http://www.kingspaninsulation.co.uk/applications/application/Roofs....
They are there to help and will be able to guide you better on suitable depths to meet U-Values. But if you are using an architect or builder they should be able to do this for you.
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